Mechanistic insights into the electrochemical reduction of CO<sub>2</sub> to CO on Ni(salphen) complexes

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چکیده

Ni(salphen) reduces CO 2 to via a double reduction/protonation mechanism, and the active species binds CO, only releasing stoichiometric amounts of upon exposure air. This has been confirmed in both experimental computational studies.

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ژورنال

عنوان ژورنال: Inorganic chemistry frontiers

سال: 2023

ISSN: ['2052-1553', '2052-1545']

DOI: https://doi.org/10.1039/d3qi00424d